An unknown alkene with formula C7H12 undergoes oxidation by hot alkaline KMnO4 to yield, after acidification 6−ketoheptanoic acid.
Which of the following is that unknown alkene?
1) Methyl cyclohexene
2) Methyl cyclopentene
3) 2-methyl pentene
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Solution
The unknown alkene is Methyl cyclohexene. On heating with alkaline KMnO4, it forms 6-ketoheptanoic acid. In this reaction, the carbon carbon double bond is broken to form one carbonyl group and one carboxylic group.