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Question

An unknown compound contains C,H and O elements, it contains 48% C and 4.0% H by mass. The molar mass 200 is determined in the lab. Find the molecular formula of this compound.

A
C2H3O2
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B
C4H6O2
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C
C4H4O3
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D
C8H3O6
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E
C8H8O6
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Solution

The correct option is E C8H8O6
100 g of compound will contain 48 g C, 4.0 g H and 100484.0=48 g O.
The atomic masses of C, H and O are 12, 1 and 16 g/mol respectively.
The number of moles of C =4 g1 g/mol=4 mol
The number of moles of H =4 g1 g/mol=4 mol
The number of moles of O =48g16g/mol=3mol
C:H:O=4:4:3
The empirical formula is C4H4O3.
Empirical formula mass =4(12)+4(1)+3(16)=100 g/mol
Molar mass = 200 g/mol
Molecular formula =200100×C4H4O3=C8H8O6

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