An unknown compound contains C,H and O elements, it contains 48% C and 4.0% H by mass. The molar mass 200 is determined in the lab. Find the molecular formula of this compound.
A
C2H3O2
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B
C4H6O2
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C
C4H4O3
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D
C8H3O6
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E
C8H8O6
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Solution
The correct option is EC8H8O6 100 g of compound will contain 48 g C, 4.0 g H and 100−48−4.0=48 g O. The atomic masses of C, H and O are 12, 1 and 16 g/mol respectively. The number of moles of C =4g1g/mol=4mol The number of moles of H =4g1g/mol=4mol The number of moles of O =48g16g/mol=3mol C:H:O=4:4:3 The empirical formula is C4H4O3. Empirical formula mass =4(12)+4(1)+3(16)=100g/mol Molar mass = 200 g/mol Molecular formula =200100×C4H4O3=C8H8O6