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Question

Analysis of a gas gave: C=85.7% and H=14.3%. If the formula mass of this gas is 42 a.m.u, what are the empirical formula and the true formula of the compound?

A
CH; C4H4
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B
CH2; C3H6
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C
CH3; C3H9
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D
C2H2; C3H6
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E
C2H4; C3H6
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Solution

The correct option is B CH2; C3H6
100 a.m.u of compound will contain 85.7 a.m.u C and 14.3 a.m.u H.

42 a.m.u (1 mole) of the compound will contain 42×85.7100=36 a.m.u C and 42×14.3100=6 a.m.u H.

The atomic masses of C and H are 12 a.m.u and 1 a.m.u respectively.

The number of moles of C present in 1 mole of compound =3612=3 moles.

The number of moles of H present in 1 mole of compound =61=6 moles.

Hence, the molecular formula of the compound is C3H6.

The empirical formula of the compound is obtained by dividing molecular formula with 3. It is CH2.

Option B is correct.

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