Aniline is not the major product in one of the following reactions. Identify that reaction.

C_{6} H_{5} O H + {N H}_{3} {Z n C l}_{2} - --- \to 300^{0} C

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C_{6} H_{5} {N O}_{2} + Z n P o w d e r a l c o h o l i c K O H - -------- \to

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C_{6} H_{5} C l + {N H}_{3} 200^{0} C - -- \to {C u}_{2} O

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C_{6} H_{5} {N O}_{2} + F e + H_{2} O H C l - - \to

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Solution

The correct option is B $C_{6} H_{5} {N O}_{2} + Z n P o w d e r a l c o h o l i c K O H - -------- \to$
Nitrobenzene reacts with zinc powder in presence of alcoholic $K O H$ to form hydrazobenzene.
$C_{6} H_{5} {N O}_{2} + Z n_{(p o w d e r)} a l c o h o l i c K O H - -------- \to C_{6} H_{5} - N H - N H - C_{6} H_{5} h y d r a z o b e n z e n e$

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C_{6} H_{5} {N O}_{2}

S n / H C l - ---- \to X

C_{6} H_{5} C O C l - ------ \to Y + H C l

C_{6} H_{5} N_{2} C l C u C l / H C l - --------- \to C_{6} H_{5} C l + N_{2}

{C H}_{3} - O - C_{6} H_{4} O H

C_{6} H_{5} - O H

{N O}_{2} - C_{6} H_{4} O H

C_{6} H_{6} \to C_{6} H_{5} {C H}_{3}

C_{6} H_{5} {N H}_{2}

C_{6} H_{5} {N H C H}_{3}

C_{6} H_{5} {C H}_{2} {N H}_{2}

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