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Question

Anodic product in the electrolytic reduction of alumina is:

A
CO2, O2
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B
O2
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C
F2
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D
O2, 4F2
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Solution

The correct option is B O2
Alumina is Al2O3.

Ionisation of alumina: Al2O36O2+4Al3+.

Reaction at cathode: 4Al3++12e4Al.

Reaction at anode: 6O23O2+12e.

Thus, the anodic product in electrolytic reduction of alumina is O2.

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