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AppearanceReactions with dilute
HCl
Reaction with dilute
HNO3
Unknown metal #1Dull gray solid with white oxide coatingDissolved with bubbles of clear gasDissolved with bubbles of clear gas
Unknown metal #2Solid; lustrous, smooth silver-gray surfaceNo Reaction Dissolved with bubbles of orange gas

The addition of dilute HNO3 to unknown metal # 2 produced an orange gas. What is the likely identity of this gas?

A
Cl2
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B
H2
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C
O2
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D
NO2
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Solution

The correct option is B NO2
The metal with grey color surface and lustrous is silver.
Silver reacts only with HNO3 to form a salt and forms clear gas of NO2. Ag do not react with HCl
2HNO3+2Ag2AgNO3+NO2+H20.
Hence option A is correct.Hence option D is correct.

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