Application of valence bond theory with examples
Application of valence bond theory with examples
An important aspect of the Valence Bond theory is the condition of maximum overlap, which leads to the formation of the strongest possible bonds. This theory is used to explain the covalent bond formation in many molecules.
For example, in the case of the F2 molecule, the F−F bond is formed by the overlap of pzorbitals of the two F atoms, each containing an unpaired electron. Since the nature of the overlapping orbitals are different in H2 and F2molecules, the bond strength and bond lengths differ between H2 and F2 molecules.
In an HF molecule the covalent bond is formed by the overlap of the 1s orbital of H and the 2pz orbital of F, each containing an unpaired electron. Mutual sharing of electrons between H and F results in a covalent bond in HF.
An important aspect of the Valence Bond theory is the condition of maximum overlap, which leads to the formation of the strongest possible bonds. This theory is used to explain the covalent bond formation in many molecules.
For example, in the case of the F2 molecule, the F−F bond is formed by the overlap of pzorbitals of the two F atoms, each containing an unpaired electron. Since the nature of the overlapping orbitals are different in H2 and F2molecules, the bond strength and bond lengths differ between H2 and F2 molecules.
In an HF molecule the covalent bond is formed by the overlap of the 1s orbital of H and the 2pz orbital of F, each containing an unpaired electron. Mutual sharing of electrons between H and F results in a covalent bond in HF.
