Aqueous solution of glucose is 35%w/w. Then calculate the boiling point of the solution.
Given: Aqueous solution of 1 molal urea solution boils at 100.60∘C and water boils at 1 atm pressure.
A
100.01∘C
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B
103.41∘C
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C
97.83∘C
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D
101.79∘C
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Solution
The correct option is D101.79∘C Water boils at 1 atmospheric pressure.
Thus, boiling point of H2O=100∘C
1 molal urea solution boils at 100.6∘C
Elevation in boling point of urea solution:
∴ΔTb=(100.6−100)∘C=0.60∘C
ΔTb=Kb×molality
0.60=Kb×1
∴Kb(H2O)=0.60Kmol−1kg
Glucose solution is 35% by weight of solution.
Thus, w1(glucose)=35g
w2(solventH2O)=65g
Molar mass of glucose(m1)=180g
Elevation in boiling point for glucose solution:
ΔTb=1000×Kb×w1m1×w2
ΔTb=1000×0.60×35180×65=1.79∘C
∴Boiling point of glucose solution=100∘C+1.79∘C=101.79∘C