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Question

Aqueous solution of glucose is 35% w/w. Then calculate the boiling point of the solution.
Given: Aqueous solution of 1 molal urea solution boils at 100.60C and water boils at 1 atm pressure.


A
100.01C
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B
103.41C
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C
97.83C
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D
101.79C
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Solution

The correct option is D 101.79C
Water boils at 1 atmospheric pressure.

Thus, boiling point of H2O=100C

1 molal urea solution boils at 100.6C

Elevation in boling point of urea solution:

ΔTb=(100.6100)C=0.60C

ΔTb=Kb×molality

0.60=Kb×1

Kb(H2O)=0.60 Kmol1kg

Glucose solution is 35% by weight of solution.

Thus,
w1(glucose)=35g

w2(solventH2O)=65g

Molar mass of glucose(m1)=180g

Elevation in boiling point for glucose solution:

ΔTb=1000×Kb×w1m1×w2

ΔTb=1000×0.60×35180×65=1.79C

Boiling point of glucose solution=100C+1.79C=101.79C


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