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Question

Aqueous solution of mdinitrosobenzene was electrolyzed for 2 hours passing current of 2A with efficiency of 90. Calculate the amount of 3-aminoaniline.
(Mw=108gmol1)

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Solution

nf (for nitrobenzene to amino benzene
W1=z×i×t=EF×i×t=M0nf×i×tF
W1=(10862×2×3600sec96500)g.(For 100% efficiency)
For90%W2=0.9{W1}g.=2.417g.

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