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Question

Aqueous solutions of zinc sulphate and iron sulphate were taken in the test tubes I and II by four students. A, B, C and D. Metal pieces of iron and zinc were dropped in the two solutions and observations made after several hours and recorded in the form of a table as given below:
Observation by Metal Solution Colour change of solution Deposit/Residue obtained
A Fe ZnSO4 turned green silvery grey coating
Zn FeSO4 no change no change
B Fe ZnSO4 no change black residue
Zn FeSO4 colour faded grey coating
C Fe ZnSO4 no change no change
Zn FeSO4 turned colourless black residue
D Fe ZnSO4 no change grey residue
Zn FeSO4 no change black residue
The correct reporting has been made observations reported by the student :
(1) A
(2) B
(3) C
(4) D

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Solution

When iron is treated with zinc sulfate, no reaction takes place because iron is less reactive than zinc.
When zinc is treated with iron sulphate, the green colour solution becomes colourless and black residue of iron is obtained.
So observations made by student C are correct.

Hence, the correct answer is option 3.

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