Arndt-Eistert synthesis is used to convert an acetyl chloride (RCOCl) into
A
a methyl ester (RCOOCH3)
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B
a diazoketone
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C
a ketene (R−CH=C=O)
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D
a higher acid (RCH2COOH)
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Solution
The correct option is D a higher acid (RCH2COOH) In Arndt-Eistert synthesis, an acyl chloride is converted into a higher acid. RCOClCH2N2−−−−→etherRCO−CH=N2Ag+(cat.)−−−−−−−−→H2O,dioxaneRCH2COOH Thus, a carbon atom is introduced in this reaction.