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Question

Arrange following in increasing order of their boiling point
2-Methylpropene , But-2-ene , 2-Methylbut-2-ene , Propene , 2,3-Dimethylbut-2-ene

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Solution

More the surface area more will be the boiling point. More the number of arbon atom more will be the boiling point. By using the above two rules, the order should be found.
So the order is
Propene < 2-Methyl propene < But-2-ene < 2-Methyl but-2-ene < 2,3-Dimethyl but-2-ene

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