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Introduction and Degree of Hydrolysis

Arrange the c...

Question

Arrange the compound in decreasing order of their reactivity for hydrolysis reaction:

A

I > I I > I I I > I V

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B

I V > I I > I > I I I

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C

I I I > I V > I I > I

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D

I V > I I I > I I > I

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Solution

The correct option is D $I V > I I > I > I I I$
Reactivity to hydrolysis $\propto$ Stability of intermediate carbocation.

So as refer to the above image, order of stability of intermediate carbocation is

$I V > I I > I > I I I$

So, order of reactivity for hydrolysis is:
$I V > I I > I > I I I$

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