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Question

Arrange the following according to decreasing order of reactivity towards HBr.

A
I>II>III
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B
II>I>III
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C
III>I>II
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D
III>II>I
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Solution

The correct option is A I>II>III
More the electron-donating ability of substituent more is the stability of carbocation. Hence more will be reactivity towards electrophilic addition reaction with HBr.

Among I, II and III, electron-donating ability order is:

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