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Question

Arrange the following alcohols in order of increasing reactivity towards sodium metal.
(i) (CH3)3C−OH (ii) (CH3)2CH−OH (iii) CH3CH2OH

A
(iii) < (ii) < (i)
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B
(ii) < (i) < (iii)
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C
(i) < (ii) < (iii)
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D
(iii) < (i) < (ii)
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Solution

The correct option is B (i) < (ii) < (iii)
More the number of methyl groups ( electrons realeasing) lesser will be the acidity. Hence the reactivity towards sodium metal willbe tert.< sec < pri.

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