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Question

Arrange the following alkali metal carbonates in increasing order of their covalent character:

Rb2CO3, Cs2CO3, Li2CO3, Na2CO3, K2CO3

A
Cs2CO3<Rb2CO3<K2CO3<Na2CO3<Li2CO3
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B
Li2CO3<Na2CO3<K2CO3<Rb2CO3<Cs2CO3
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C
Rb2CO3<Cs2CO3<Li2CO3<Na2CO3<K2CO3
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D
None of these
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Solution

The correct option is A Cs2CO3<Rb2CO3<K2CO3<Na2CO3<Li2CO3
Covalent character of carbonates of a particular group decreases due to increase in atomic size. Hence, ionic nature increases. It decreases from Li to Cs.

Thus, the correct order of covalent nature of carbonates of IA group elements is:
Cs2CO3<Rb2CO3<K2CO3<Na2CO3<Li2CO3
Hence, option A is correct.

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