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Question

Arrange the following alkali metal carbonates in increasing order of their thermal stability:
Li2CO3,Rb2CO3,Cs2CO3,Na2CO3,K2CO3

A
Li2CO3<Na2CO3<K2CO3<Rb2CO3<Cs2CO3
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B
Cs2CO3<Na2CO3<K2CO3<Rb2CO3<Li2CO3
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C
Li2CO3<K2CO3<Na2CO3<Rb2CO3<Cs2CO3
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D
None of these
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Solution

The correct option is A Li2CO3<Na2CO3<K2CO3<Rb2CO3<Cs2CO3
Thermal stability is a stability of a molecule at high temperature. A molecule with more stability has more resistance to decomposition at high temperatures.
As we move from top to bottom in a group, the thermal stability increases.
Thermal stability decreases from Li to Cs.
So, the correct order of thermal stability will be-
Li2CO3<Na2CO3<K2CO3<Rb2CO3<Cs2CO3.
Hence, option (A) is correct.

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