Arrange the following compound according to their basic strength (with suitable explanation):
$C_{6} H_{5} {N H}_{2}, C_{6} H_{5} N H M e, C_{6} H_{5} N M e_{2}, o - M e C_{6} H_{4} {N H}_{2}$

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Solution

$∴$ $O - M_{c} C_{6} H_{4} N H_{2}$ is less than basic due to ortho effect decrease the basic character. Due to steric effect (equation refer to image ) is less basic.

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