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Question

Arrange the following compounds in increasing order of their acid strength.
Propan-1-ol, 2,4,6-trinitrophenol, 3-nitrophenol, 3, 5-dinitrophenol, phenol, 4- methyl phenol .

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Solution

The acidic strength of the given compound in decreasing order is given below

propanol<4methyl phenol<phenol<3nitrophenol<2,4,6trinitrophenol

Due to all alcohols are less acidic than phenols

And I power increases acidic strength,

While +I power decreases acidic character.

So,

propanol<4methyl phenol<phenol<3nitrophenol<2,4,6trinitrophenol

This the required order.

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