Arrange the following compounds in their decreasing order of boiling points: I.C9H20II.C8H18
III.(CH3)2C−(CH2)4−CH3
IV.CH3−CH3|C|CH3−CH3|C|CH3−CH3
A
(I)>(II)>(III)>(IV)
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B
(IV)>(III)>(II)>(I)
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C
(I)>(III)>(II)>(IV)
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D
(IV)>(II)>(III)>(I)
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Solution
The correct option is A(I)>(II)>(III)>(IV) The given hydrocarbons are alkanes. Greater the number of carbon atoms, higher the boiling point due to higher molecular mass. For the same number of carbon atoms, branching reduces the boiling point.