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Question

Arrange the following in increasing/decreasing order of boiling point :
CH3CH2CH2CH2CH3I, (CH3)2CHCH2CH3II, (CH3)4CIII

A
I > II > III
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B
II > I > III
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C
III > I > II
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D
III < II < I
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Solution

The correct options are
A I > II > III
D III < II < I
The decrease order of the boiling point is CH3CH2CH2CH2CH3I>(CH3)2CHCH2CH3II>(CH3)4CIII.
As the extent of branching increases, the boiling point decreases.

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