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Question

Arrange the following in the decreasing order of C-C length.

I. C2H4
II. C2H2
III. C6H6
IV. C2H6

A
IV > III > I > II
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B
I > II > IV > III
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C
II > I > IV > III
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D
IV > I > III > II
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Solution

The correct option is A IV > III > I > II
The correct order of decreasing CC bond length is IV>III>I>II.
IV: Butane - has all single bonds making the longest bond lengths.
III: Benzene - has resonance meaning that the C-C bond has equal single bond and douible bond character.
II: Butyne - has a triple bond
I: Butene: has a double bond
More the number of bonds, shorter the bond length.

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