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Question

arrange the following in the decreasing order of their electron affinity


(Na+,Na++,Na,Na−)

A
(Na++,Na+,Na,Na)
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B
(Na,Na,Na+,Na++)
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C
(Na+,Na++,Na,Na)
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D
(Na,Na+,Na++,Na)
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Solution

The correct option is A (Na++,Na+,Na,Na)
The electron affinity of an atom or molecule is defined as the amount of energy released or spent when an electron is added to a neutral atom or molecule in the gaseous state to form a negative ion.

X+eX+energy
When we add electrons to cation more energy is released as the cation has a smaller size.

Thus, the decreasing order of electron affinity is as follows:
(Na++,Na+,Na,Na)

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