arrange the following in the decreasing order of their electron affinity
(Na+,Na++,Na,Na−)
A
(Na++,Na+,Na,Na−)
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B
(Na−,Na,Na+,Na++)
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C
(Na+,Na++,Na,Na−)
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D
(Na−,Na+,Na++,Na)
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Solution
The correct option is A(Na++,Na+,Na,Na−) The electron affinity of an atom or molecule is defined as the amount of energy released or spent when an electron is added to a neutral atom or molecule in the gaseous state to form a negative ion.
X+e−→X−+energy
When we add electrons to cation more energy is released as the cation has a smaller size.
Thus, the decreasing order of electron affinity is as follows: