1 litre = 1000 cm3 = 1000 cc
We know that, volume of 1 mole of gas at S.T.P = 22.4 L = 22400 cm3 = 22400 cc.
200 cc of NH3 at S.T.P contains (6.022×1023×200)22400=0.0537×1023 molecules
150 cc of O2 at S.T.P (6.022×1023×150)22400=0.0403×1023 molecules
100 cc of N2 at S.T.P
(6.022×1023×100)22400=0.0268×1023 molecules
50 cc of SO2 at S.T.P (6.022×1023×50)22400=0.013×1023 molecules.