wiz-icon
MyQuestionIcon
MyQuestionIcon
20
You visited us 20 times! Enjoying our articles? Unlock Full Access!
Question

Arrange the following in the increasing order of their ability as a leaving group:
CH3S−,CH3O−,CF−3 and F−

141486_f3dd0ac9540e4b74ae381c8b0680eef6.png

A
CH3S > CH3O > CF3 > F
No worries! We‘ve got your back. Try BYJU‘S free classes today!
B
CH3O > CH3S > F > CF3
No worries! We‘ve got your back. Try BYJU‘S free classes today!
C
CH3S > CH3O > F > CF3
Right on! Give the BNAT exam to get a 100% scholarship for BYJUS courses
D
CH3S < CH3O < CF3 < F
No worries! We‘ve got your back. Try BYJU‘S free classes today!
Open in App
Solution

The correct option is B CH3S > CH3O > F > CF3
The decreasing order for the ability as leaving group is CH3S>CH3O>F>CF3

Higher is the electronegativity of the atom bearing negative charge, more tightly are held the electron pairs and their donation is less likely. This decreases the electrophilic character. The decreasing order of electronegativity is S>O>F.

CF3 is least nucleophilic in nature as three highly electronegative F atoms significantly decrease the electron density on C atom.

flag
Suggest Corrections
thumbs-up
0
Join BYJU'S Learning Program
similar_icon
Related Videos
thumbnail
lock
SN1 Mechanism
CHEMISTRY
Watch in App
Join BYJU'S Learning Program
CrossIcon