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Amines as Bases

Arrange the f...

Question

Arrange the following in the increasing order of their basic strength.
${C H}_{3} {N H}_{2}, {({C H}_{3})}_{2} N H, C_{6} H_{5} {N H}_{2}, C_{6} H_{5} {C H}_{2} {N H}_{2}$

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Solution

Since the basic character depend on the inductive effect therefore correct order is
$C_{6} H_{5} N H_{2} < C_{6} H_{5} C H_{2} N H_{2} < C H_{3} N H_{2} < {(C H_{3})}_{2} N H$

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