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Question

Arrange the following in the order of increasing value of the equilibrium constant for hydration, Khyd (smallest value first).
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A
2<1<3
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B
3<1<2
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C
1<2<3
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D
2<3<1
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Solution

The correct option is B 3<1<2
As the polarity of CO bond decreases hydration decreases. In compound 3 polarity is least due to +I effect of tert-butyl. Compound 2 is most polar among the given compounds as +I effect will be less in 2 compared to 1. So the order would be 3<1<2

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