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Question

Arrange the following in the order of reactivity towards an electrophilic attack

A
V > IV > III > II > I
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B
III > V > IV > II > I
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C
III > IV > V > II > I
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D
V > IV > III > I > II
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Solution

The correct option is B III > V > IV > II > I
Reactivity towards electrophilic substituion reaction depends upon stability of arenium ion intermediate. Stability of arenium ion increases in the presence EDG group (causing +R, +I, H) and decreases in the presence of EWG (causing -R, -I). Hence, the correct order will be III > V > IV > II > I


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