Arrange the following (w, x, y, z,) in decreasing order of their boiling points:

w > x > z > y

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w > x > y > z

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w > z > y > x

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w > z > x > y

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Solution

The correct option is D $w > z > x > y$
Solution of $H -$ bonding $\propto$ boiling point (or vice-versa)
$B P$ : $- O - H > - N - H > N - {C H}_{3} < - O - {C H}_{3}$
$H -$ bond: $- O H > - N H >$
$B P$ : $w > z > x > y$
Therefore, $E . N . : O > N$

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