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Question

Arrange the reactions given below in proper sequence for the conversion of ethane to methane.
(a) Treatment with sodium hydroxide (b) Treatment with aqueous KOH (c) Treatment with NaOH+CaO (d) Halogenation (e) Reaction with acidified K2Cr2O7

A
e a d b c
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B
d b e a c
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C
e c b a d
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D
d e a b c
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Solution

The correct option is C d b e a c
Halogenation of ethane gives ethyl halide.
Treatment with aqueous KOH produces ethanol.
Reaction with acidified potassium dichromate produces ethanoic acid.
Now reaction with NaOH produces sodium salt of carboxylic acid, CH3COONa.
Finally, reaction with NaOH+CaO, does decarboxylation which removes a carbon atom from the chain and forms alkane with one carbon atom less, hence methane is formed.


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