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Question

Arrange the reactivity of given four compounds in decreasing order for nucleophilic addition reaction.
(1) Amide (2) Ester (3) Aldehyde (4) Ketone

A
1>2>3>4
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B
3>4>2>1
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C
4>3>2>1
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D
3>4>1>2
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Solution

The correct option is B 3>4>2>1
Given
Solution :
Alkyl groups and alokxy groups add electron density to carbonyl carbon.
Because of their low reactivity, amide do not participate in nearly as many nucleophilic substitution reactions
The decreasing order of electrophilic character of carbonyl carbon is
aldehyde>ketone>ester>Amide
Hence, the decreasing order of reactivity for the nucleophilic addition reaction is
aldehyde>ketone>ester>amide
The correct option is option B. 3>4>2>1

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