Arrange them in the increasing order of their of their solubility in water: NaCl , MgO , MgCl2
A
NaCl , MgCl2 , MgO
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B
MgO , MgCl2 , NaCl
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C
MgCl2 , NaCl , MgO
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D
none of these
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Solution
The correct option is BMgO , MgCl2 , NaCl The more the lattice entalphy the less will be the ability to dissolve in water.
Lattice enthalpy is a measure of the strength of the forces between the ions in an ionic solid. The greater the lattice enthalpy, the stronger the forces.
Lattice enthalpy of NaCl = 787kJ/mol
Lattice enthalpy of MgCl2=+2534kJ/mol
Lattice enthalpy of MgO = 3826kJ/mol
Since Lattice enthalpy is inversely proportional to solubility option B is correct.