Arrange these compounds in decreasing order of reactivity for the nucleophilic addition reaction : ( I ) Acid chloride ( II ) Aldehyde ( III ) Ketone ( IV ) Ester Select the correct answer from the codes given below :
A
I>II>III>IV
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B
IV>III>II>I
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C
III>II>I>IV
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D
I>IV>II>III
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Solution
The correct option is AI>II>III>IV Chlorine atom withdraws electron density from carbonyl carbon. Alkyl groups and alokxy groups add electron density to carbonyl carbon. The decreasing order of electrophilic character of carbonyl carbon is acidchloride>aldehyde>ketone>ester Hence, the decreasing order of reactivity for the nucleophilic addition reaction is acidchloride>aldehyde>ketone>ester The correct option is option A. I>II>III>IV