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Question

Arrange these compounds in decreasing order of reactivity for the nucleophilic addition reaction :
( I ) Acid chloride ( II ) Aldehyde ( III ) Ketone ( IV ) Ester
Select the correct answer from the codes given below :

A
I>II>III>IV
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B
IV>III>II>I
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C
III>II>I>IV
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D
I>IV>II>III
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Solution

The correct option is A I>II>III>IV
Chlorine atom withdraws electron density from carbonyl carbon. Alkyl groups and alokxy groups add electron density to carbonyl carbon.
The decreasing order of electrophilic character of carbonyl carbon is acidchloride>aldehyde>ketone>ester
Hence, the decreasing order of reactivity for the nucleophilic addition reaction is acidchloride>aldehyde>ketone>ester
The correct option is option A. I>II>III>IV

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