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Question

Arrange X , Y , and Z in order of increasing acidic strengths.
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A
X>Z>Y
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B
Z<X>Y
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C
X>Y>Z
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D
Z>X>Y
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Solution

The correct option is C X>Z>Y
Carboxylic acid is stronger acid than +NH3, therefore, X is the strongest acid. Since -COOH has I effect which decreases with distance, therefore, I effect is more pronounced on Z than on Y. As a result, Z is more acidic than Y.

Thus, overall order of decreasing acidic strength is X>Z>Y.

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