Arrangement of $(C H_{3})_{3} C -, (C H_{3})_{2} C H -, C H_{3} - C H_{2} -$ when attached to benzyl or an unsaturated group in increasing order of inductive effect is:

(C H_{3})_{3} C - < (C H_{3})_{2} C H - < C H_{3} - C H_{2}

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C H_{3} - C H_{2} - < (C H_{3})_{2} C H - < (C H_{3})_{3} C -

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(C H_{3})_{2} C H - < (C H_{3})_{3} C - < C H_{3} - C H_{2}

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(C H_{3})_{3} C - < C H_{3} - C H_{2} < (C H_{3})_{2} C H -

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Solution

The correct option is B $C H_{3} - C H_{2} - < (C H_{3})_{2} C H - < (C H_{3})_{3} C -$
$- C H_{3}$ group has +I effect, as number of $- C H_{3}$ froup increases, the inductive effect increases. this effect diminishes after 3rd carbon. Therefore the correct order is
$C H_{3} - C H_{2} - < (C H_{3})_{2} C H - < (C H_{3})_{3} C -$

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