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Question

As the number of carbon atoms in a chain increases, the boiling point of alkanes _________.


A

Increases

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B

Decreases

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C

Remains same

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D

May increase or decrease

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Solution

The correct option is A

Increases


As the number of carbon atoms in a chain increases, the size of molecules increases. With increase in size, the intermolecular force of attraction also increases. So, more energy will be needed to break the force of attraction between the atoms. Thus, the boiling point of alkanes increases with increasing carbon atoms in a chain.


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