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Question

Assertion :2-butyne on treatment with NaNH2 followed by acidifictaion yields 1-butyne. Reason: Alkynes isomerizes on treatment with a strong base.

A
Both Assertion and Reason are correct and Reason is the correct explanation for Assertion
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B
Both Assertion and Reason are correct but Reason is not the correct explanation for Assertion
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C
Assertion is correct but Reason is incorrect
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D
Both Assertion and Reason are incorrect
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Solution

The correct option is B Both Assertion and Reason are correct but Reason is not the correct explanation for Assertion
2 - butyne on treatment with sodamide followed by acidification yields 1- butyne because alkynes isomerize on treatment with a strong base.
Terminal alkyne isomer forms sodium salt with soda amide and is phased out of isomerization equilibrium which is why 1-butyne is the only product instead of an equilibrium mixture of two products.
Hence, Both Assertion and Reason are correct but Reason is not the correct explanation for Assertion.

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