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Question

Assertion (A) : In CsCl crystal, the coordination number of Cs ion is 8.
Reason (R) :
Cl ions in CsCl adopt bcc type of packing.

A
Both (A) and (R) are correct and (R) is the correct explanation of (A)
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B
Both (A) and (R) are correct but (R) is not the correct explanation of (A)
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C
(A) is correct but (R) is incorrect
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D
(A) is incorrect but (R) is correct
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E
Both (A) and (R) are incorrect
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Solution

The correct option is A Both (A) and (R) are correct and (R) is the correct explanation of (A)
Limiting radius ratio = r/R Coordination Number of cationStructural Arrangement (Geometry of voids) Example
0.155-0.225
0.225-0.414
0.414-0.732
0.414-0.732
0.732-1.000
3
4
4
6
8
Plane Trigonal
Tetrahedral
Square planar
Octahedral
Cubic
Boron Oxide
ZnS,SiO2
-
NaCI,MgO2
CsCI

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