Assertion (A):Li is the weakest reducing agent among the alkali Reason (R) : In alkali metals, ionisation energy increases down the group
A
Both A and R are true and R is the correct explanation of A
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B
Both A and R are true but R is not a correct explanation of A
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C
A is true but R is false
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D
Both A and R are false
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Solution
The correct option is D Both A and R are false In alkali metals, ionization energy decreases down the group. Among alkali metals, lithium has highest value of ionization energy. But it has large heat of hydration due to small size. Thus, the hydration energy more than compensates the ionization energy. Hence it is strongest reducing agent among the alkali metals.