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Question

Assertion (A): N3 is isostructural with I3
Reason(R) : The E.N of N is greater than I

A
Both (A) and (R) are true and (R) is the correct explanation of (A)
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B
Both (A) and (R) are true and (R) is not the correct explanation of (A)
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C
(A) is true and (R) is false
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D
(A) is false but (R) is true
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Solution

The correct option is D Both (A) and (R) are true and (R) is not the correct explanation of (A)
N3 structure is linear and sp N
I3 geometry is trigonal bipyramidal and three lone pair of electrons.
Therefore, the shape is linear and sp3d I
The assertion is true and N has a higher electronegativity than I but they are not related.

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