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Question

Assertion (A) Order and molecularity are same.

Reason (R) Order is determined experimentally and molecularity is the sum of the stoichimetric coeffcient of rate determining elementary step.

(a) Both assertion and reason are correct and the reason is correct explanation of assertion
(b) Both assertion and reason are correct, but reason does not explain assertion.
(c) Assertion is correct, but reason is incorrect
(d) Both assertion and reason are incorrect
(e) Assertion is incorrect but reason is correct.

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Solution

Answer (e). Assertion is incorrect and reason is correct.

Order and molecularity may or may not be same as order of reaction is sum of power of reactant which can be determined experimentally. But molecularity is sum of stoichiometric coefficient of rate determining elementary step.


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