Assertion (A): Permanent hardness of water is removed by treatment with washing soda.
Reason (R): Washing soda reacts with soluble magnesium and calcium sulphate to form insoluble carbonates.
Both A and R are correct and R is the correct explanation of A.
Washing soda (Na2CO3) reacts with soluble calcium and magnesium chlorides and sulphates in hard water to form insoluble carbonates and thus removes hardness of water.
MCl2+Na2CO3→MCO3↓+2NaCl
(M=Mg,Ca)
MSO4+Na2CO3→MCO3↓+Na2SO4
So, option (A) is correct. Hence, statements A and R both are correct and R is the correct explanation of A.