The correct option is A Statements (A) and (R) both are correct and (R) is the correct explanation of (A).
Permanent hardness is due to the presence of chlorides and sulphates of calcium and magnesium. This could be treated by adding Na2CO3, which is soluble in water. It forms insoluble compounds with these compounds. Hence, both the assertion and the reason are correct. Also, the reason correctly explains the assertion.