Assertion :A reaction which is spontaneous and accompanied by decrease of randomness must be exothermic. Reason: All exothermic reactions are accompanied by decrease of randomness.

Both Assertion and Reason are correct and Reason is the correct explanation for Assertion

No worries! We‘ve got your back. Try BYJU‘S free classes today!

Both Assertion and Reason are correct but Reason is not the correct explanation for Assertion

No worries! We‘ve got your back. Try BYJU‘S free classes today!

Assertion is correct but Reason is incorrect

Right on! Give the BNAT exam to get a 100% scholarship for BYJUS courses

Both Assertion and Reason are incorrect

No worries! We‘ve got your back. Try BYJU‘S free classes today!

Open in App

Solution

The correct option is C Assertion is correct but Reason is incorrect
$Δ G = Δ H - T Δ S$
$Δ S < 0 a n d Δ H < 0$
from the above eqn, $Δ H$ must be <0
Hence, the reaction will be exothermic in nature.
Reason is incorrect as an exothermic reaction can be accompanied by either increase or decrease of entropy.
Hence, option C is correct

Suggest Corrections

Similar questions

Q. Assertion :A reaction which is spontaneous and accompanied by decrease of randomness must be exothermic. Reason: All exothermic reactions are accompanied by decrease of radomness.

Q. For the following Assertion and Reason, the correct option is:
Assertion: The

p H

of water increases with increase in temperature.

Reason: The dissociation of water into

H^{+}

and

O H^{-}

an exothermic reaction.

Q. Assertion: The compressibility factor for

H_{2}

and

H e

(1 + \frac{P b}{R T})

Reason: The compressibility factor for

H_{2}

and

H e

can be derived from Van der Waal's equation.

Assertion (A) Order of the reaction can be zero or fractional.

Reason (R) We cannot determine order from balanced chemical equation.

(a) Both assertion and reason are correct and the reason is correct explanation of assertion
(b) Both assertion and reason are correct, but reason does not explain assertion.
(c) Assertion is correct, but reason is incorrect
(d) Both assertion and reason are incorrect
(e) Assertion is incorrect but reason is correct.

Assertion (A) Ethanol is a weaker acid than phenol.
Reason (R) Sodium ethoxide may be prepared by the reaction of ethanol with aqueous NaOH.
(a) Assertion and reason both are correct and reason is correct explanation of assertion.
(b) Assertion and reason both are wrong statements.
(c) Assertion is correct statement but reason is wrong statement.
(d) Assertion is wrong statement but reason is correct statement.
(e) Both assertion and reason are correct statements but reason is not correct explanation of assertion.

Join BYJU'S Learning Program