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Question

Assertion :A tertiary acid (R3CCOOH) usually fail in sodalime catalyzed decarboxylation reaction to produce alkane, rationalize. Reason: Tertiary carbanion is highly unstable,very less likely to be formed.

A
Both Assertion and Reason are correct and Reason is the correct explanation for Assertion
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B
Both Assertion and Reason are correct but Reason is not the correct explanation for Assertion
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C
Assertion is correct but Reason is incorrect
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D
Both Assertion and Reason are incorrect
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Solution

The correct option is A Both Assertion and Reason are correct and Reason is the correct explanation for Assertion
The decarboxylation of a tertiary acid in presence of sodalime involves a carbocation intermediate which is highly unstable and less likely to be formed. Hence, the decarboxylation fails. Thus, both the assertion and reason are correct and the reason is the correct explaination of the assertion.

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