Assertion (A): The enthalpy of formation of H2O(l)is greater than that of H2O(g)
Reason (R): Enthalpy change is negative for the condensation reaction H2O(g)→H2O(l)
A
Both assertion and reason are correct, reason is the correct explanation of the assertion
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B
Both assertion and reason are correct reason is the not correct explanation of the assertion
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C
Assertion is correct, reason is incorrect
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D
Assertion is incorrect , reason is correct
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Solution
The correct option is B Both assertion and reason are correct, reason is the correct explanation of the assertion Difference between the heat of reaction of liquid water and condensation is the heat of condensation reaction which is negative. Hence standard heat of formation is more negative for liquid water than steam. Note standard heat of formation are always compared in negative values.