Assertion :According to Kohlrausch's law, the molar conductance of a strong electrolyte at infinite dilution is sum of molar conductivities of its ions. Reason: The current carried by cation and anion is always equal.
A
Both Assertion and Reason are correct and Reason is the correct explanation for Assertion
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B
Both Assertion and Reason are correct but Reason is not the correct explanation for Assertion
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C
Assertion is correct but Reason is incorrect
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D
Assertion is incorrect but Reason is correct
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Solution
The correct option is C Assertion is correct but Reason is incorrect Yes, the assertion is correct but the current carried by a ion depends upon its mobility and mobility of ion changes with change in size of ions;
cation is having smaller size than anion and moves with greater speed and hence carry large current;
hence, the current carried by cation and anion is different.