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Question

Assertion :Acetic acid does not undergo haloform reaction. Reason: Acetic acid has no α hydrogen.

A
Both Assertion and Reason are correct and Reason is the correct explanation for Assertion.
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B
Both Assertion and Reason are correct but Reason is not the correct explanation for Assertion.
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C
Assertion is correct but Reason is incorrect.
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D
Both Assertion and Reason are incorrect.
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Solution

The correct option is C Assertion is correct but Reason is incorrect.
Haloform test identifies the presence of a CH3CO group in aldehydes and ketones.

CH3COR+3I2+4OHCHI3+RCOO+3I+3H2O

Acetic acid does not undergo haloform reaction because in presence of OH ions it acts as an acid and does not forms CHX3 haloform. Therefore assertion is correct.

Acetic acid has three α hydrogens, thus the reason is incorrect.


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