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Question

Assertion :Addition of HCl to 3,3,3-trifuoro-1-propene gives 1-chloro-3,3,3-trifluoro propane as major product. Reason: Addition follow Markownikoff 's rule.

A
Both Assertion and Reason are correct and Reason is the correct explanation for Assertion
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B
Both Assertion and Reason are correct but Reason is not the correct explanation for Assertion
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C
Assertion is correct but Reason is incorrect
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D
Both Assertion and Reason are incorrect
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Solution

The correct option is C Assertion is correct but Reason is incorrect

CF3CH=CH2+H+CF3CH2C+H2ClCF3CH2CH2Cl

When a molecule of HCl adds to a C=C double bond, the hydrogen becomes attached to the carbon with more hydrogens attached to it already. This is known as Markonikoff's rule.

Assertion - Addition of HCl to 3,3,3-trifuoro-1-propene gives 1-chloro-3,3,3-trifluoro propane as major product. (True) As shown in reaction above, hydrogen addition take place according to Anti-Markonikoff rule because carbocation is most stable at rightmost carbon.

Reason - Addition follow Markownikoff 's rule. (False)


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