Assertion :AgNO3 reacts with KCN to form white ppt. of AgCN. This white ppt. disappears when excess KCN is added. Reason: AgCN decomposes to form siver-carbide and evovle N2 gas.
A
Both Assertion and Reason are correct and Reason is the correct explanation for Assertion
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B
Both Assertion and Reason are correct but Reason is not the correct explanation for Assertion
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C
Assertion is correct but Reason is incorrect
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D
Assertion is correct but Reason is correct
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Solution
The correct option is C Assertion is correct but Reason is incorrect Silver nitrate reacts with KCN to form a white precipitate of silver cyanide. In excess KCN, this white precipitate dissolves to form potassium argentocyanide. AgNO3+KCN→AgCN+KNO2 AgCN+KCN→KAg(CN)2